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K. I. Tishchenko, E. K. Beloglazkina, A. G. Majouga, A. A. Moiseeva, N. V. Zyk

Novel aurophilic organic ligands on the base of 1,3-dibrompropan-2-ol and 2-aminothiophenol


The reactions of nucleophilic substitution in 1,3-dibromo-propan-2-ol and its acylation products under 2-aminothiophenol action have been investigated. It was shown that the obtained N,S-containing derivatives of 1,3-dibromo-propan-2-ol react with copper(II) salts with the formation of coordination compounds. The possibility of chemosorption of synthesized ligands and complexes, containing the additional disulfide fragments, on gold electrode surface with the formation of Au-S bonds was demonstrated.
Key words: 1,3-dibrompropan-2-ol, 2-aminothiophenol, disulfides, copper(II) complexes.
Moscow University Chemistry Bulletin.
2014, Vol. 55, No. 1, P. 29

Copyright (C) Chemistry Dept., Moscow State University, 2002
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