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K. I. Tishchenko, E. K. Beloglazkina, A. G. Majouga, A. A. Moiseeva, N. V. Zyk
Novel aurophilic organic ligands on the base of 1,3-dibrompropan-2-ol and 2-aminothiophenol
Abstract
The reactions of nucleophilic substitution
in 1,3-dibromo-propan-2-ol and its acylation products under 2-aminothiophenol
action have been investigated. It was shown that the obtained N,S-containing
derivatives of 1,3-dibromo-propan-2-ol react with copper(II) salts with the
formation of coordination compounds. The possibility of chemosorption of
synthesized ligands and complexes, containing the additional disulfide
fragments, on gold electrode surface with the formation of Au-S bonds was
demonstrated.
Key words: 1,3-dibrompropan-2-ol,
2-aminothiophenol, disulfides, copper(II) complexes.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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