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E. A. Petrushkina, D. V. Khomishin, N. E. Mysova, A. V. Orlinkov, V. N. Kalinin, A. B. Ponomarev, I. A. Godovikov, Ya. V. Zubavichus, A. A. Velizhagnin
Synthesis of
2-butyl-deca-4,9-dienoic and 2-butyl-4,9-dimethyl-deca-4,9-dienoic acids –
structural analogues of cygerolum
Abstract
New
compounds, 2-butyl-deca-4,9-dienoic and 2-butyl-4,9-dimethyl-deca-4,9-dienoic
acids which are structural analogues of 2-cyclohexylgeranylacetic acid - an
active component of skin restoration ointment “cigerol” are synthesized.
One-pot method of long chain hydrocarbons formation – reaction of 1,3-dienes
telomerization with the nucleophiles, catalyzed by palladium complexes was used
for formation of hydrocarbon chain C10. Heterogeneous
palladium-zeolite catalyst was used in isoprene telomerization with piperidine.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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