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M. A. Proskurnin, M. Yu. Kononets, V. V. Chernysh

Correlations of the Conplexes Stability Constants Determined by Thermal Lensing

Abstract

Correlation relationships of stability constants for complexes of iron(II) and copper(I) with 1,10-phenanthroline, copper(II) with 2,9-dimethyl-1,10-phenanthroline, and bismuth(III) with iodide ions are considered. The compared data were found experimentally at the level of n´ 10–8n´ 10–6 M by thermal lensing, previously found by for other methods and calculated from the theoretical (statistical) approach. The considered correlations show that the stability constants found by thermal lensing are determined with high accuracy.
Moscow University Chemistry Bulletin.
2004, Vol. 45, No. 1, P. 51
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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