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Brykina G. D., Matusova S. M., Uvarova M. I., Shpigun O. A.

Retention of tetra-4-tert-butylphthalocyanine and its complexes with zinc and cobalt in the systems Diasorb-130-Nh2-spirit.


The retention of tetra-4-tert-butylphthalocyanine and its complexes with Zn and Co was studied in spirits and their mixtures on a column Diasorb-130–NH2. It is demonstrated that chromatographic peaks of compounds are symmetrical not always, have the broadened tail, however CoPct, ZnPct and H2Pct solving in toluene or in such mobile phases as i-propanol, i-propanol–methanol (4:1) can be identify on the retention parameters depending on the nature of the reaction center.
Moscow University Chemistry Bulletin.
2001, Vol. 42, No. 6, P. 412

Copyright (C) Chemistry Dept., Moscow State University, 2002
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