Оксид трихлорид ванадия VOCl3(г)
Класс точности
6-D

Оксид трихлорид ванадия VOCl3(г)

Таблица 1286
VOCL3=V+O+3CL      DrH°  =  1778.929 кДж × моль-1
T C°p (T)  (T) S° (T) H° (T)  -  H° (0) lg K° (T) T
K Дж × K-1 × моль-1 кДж × моль-1 K
100.000
200.000
298.150
300.000
400.000
500.000
600.000
700.000
800.000
900.000
1000.000
1100.000
1200.000
1300.000
1400.000
1500.000
1600.000
1700.000
1800.000
1900.000
2000.000
2100.000
2200.000
2300.000
2400.000
2500.000
2600.000
2700.000
2800.000
2900.000
3000.000
3100.000
3200.000
3300.000
3400.000
3500.000
3600.000
3700.000
3800.000
3900.000
4000.000
4100.000
4200.000
4300.000
4400.000
4500.000
4600.000
4700.000
4800.000
4900.000
5000.000
5100.000
5200.000
5300.000
5400.000
5500.000
5600.000
5700.000
5800.000
5900.000
6000.000
59.306
79.800
89.973
90.112
95.878
99.379
101.624
103.129
104.178
104.933
105.493
105.919
106.249
106.510
106.719
106.890
107.031
107.149
107.248
107.333
107.405
107.467
107.522
107.569
107.611
107.648
107.681
107.710
107.736
107.760
107.781
107.800
107.818
107.834
107.849
107.862
107.874
107.885
107.896
107.906
107.915
107.923
107.931
107.938
107.944
107.951
107.957
107.962
107.967
107.972
107.977
107.981
107.985
107.988
107.992
107.996
107.999
108.002
108.005
108.008
108.010
219.858
254.353
278.977
279.388
299.492
316.380
330.967
343.815
355.298
365.678
375.151
383.862
391.925
399.428
406.446
413.037
419.249
425.125
430.697
435.997
441.050
445.877
450.498
454.930
459.188
463.284
467.230
471.038
474.717
478.274
481.718
485.056
488.294
491.438
494.493
497.464
500.355
503.172
505.917
508.593
511.206
513.756
516.248
518.684
521.066
523.396
525.678
527.912
530.101
532.247
534.351
536.415
538.440
540.428
542.380
544.297
546.181
548.033
549.853
551.643
553.405
263.154
311.381
345.349
345.906
372.692
394.493
412.825
428.611
442.454
454.771
465.857
475.932
485.163
493.678
501.579
508.948
515.851
522.344
528.471
534.272
539.779
545.021
550.022
554.802
559.381
563.775
567.998
572.062
575.980
579.761
583.414
586.949
590.372
593.690
596.909
600.036
603.074
606.030
608.907
611.710
614.442
617.107
619.708
622.248
624.729
627.155
629.527
631.850
634.122
636.349
638.530
640.668
642.765
644.822
646.840
648.822
650.768
652.680
654.558
656.404
658.220
4.330
11.406
19.789
19.955
29.280
39.057
49.115
59.357
69.725
80.183
90.705
101.277
111.886
122.524
133.186
143.867
154.563
165.273
175.992
186.722
197.459
208.202
218.952
229.706
240.466
251.229
261.995
272.765
283.537
294.312
305.089
315.867
326.648
337.432
348.215
359.001
369.788
380.576
391.365
402.155
412.946
423.738
434.530
445.325
456.118
466.913
477.708
488.504
499.300
510.097
520.896
531.693
542.491
553.289
564.089
574.888
585.688
596.488
607.288
618.089
628.890
-909.0797
-442.2885
-288.2961
-286.3595
-208.2877
-161.3970
-130.1112
-107.7489
-90.9672
-77.9079
-67.4557
-58.9004
-51.7683
-45.7316
-40.5558
-36.0691
-32.1423
-28.6769
-25.5961
-22.8392
-20.3577
-18.1122
-16.0707
-14.2066
-12.4977
-10.9253
-9.4738
-8.1296
-6.8814
-5.7191
-4.6341
-3.6190
-2.6672
-1.7729
-.9311
-.1371
   .6129
1.3226
1.9951
2.6334
3.2400
3.8172
4.3672
4.8918
5.3929
5.8720
6.3305
6.7697
7.1909
7.5952
7.9836
8.3570
8.7164
9.0625
9.3960
9.7176
10.0281
10.3279
10.6177
10.8979
11.1690
100.000
200.000
298.150
300.000
400.000
500.000
600.000
700.000
800.000
900.000
1000.000
1100.000
1200.000
1300.000
1400.000
1500.000
1600.000
1700.000
1800.000
1900.000
2000.000
2100.000
2200.000
2300.000
2400.000
2500.000
2600.000
2700.000
2800.000
2900.000
3000.000
3100.000
3200.000
3300.000
3400.000
3500.000
3600.000
3700.000
3800.000
3900.000
4000.000
4100.000
4200.000
4300.000
4400.000
4500.000
4600.000
4700.000
4800.000
4900.000
5000.000
5100.000
5200.000
5300.000
5400.000
5500.000
5600.000
5700.000
5800.000
5900.000
6000.000

M = 173.2998
DH° (0)  =  -659.098 кДж × моль-1
DH° (298.15 K)  =  -662.000 кДж × моль-1
S°яд  =  65.990 Дж × K-1 × моль-1

(T)  =  560.648071289 + 91.1405639648 lnx - 0.00411204248667 x-2 + 1.14476108551 x-1 + 170.084625244 x - 423.301452637 x2 + 550.209350586 x3
(x = T ×10-4;   298.15  <  T <   1500.00 K)

(T)  =  605.169433594 + 107.9765625 lnx - 0.0129277035594 x-2 + 1.98729801178 x-1 + 0.275827407837 x - 0.169519484043 x2 + 0.0544810891151 x3
(x = T ×10-4;   1500.00  <  T <   6000.00 K)

21.06.11