Железо
Fe(г). Термодинамические свойства газообразного
железа в стандартном состоянии в интервале температур 100 - 10000 К приведены в
табл. Fe.
Уровни энергии атома Fe,
использованные для расчета термодинамических функций, приведены в табл. Fe.3. Эти 483 уровня с суммарным статистическим
весом 3428, лежащие в интервале 0 – 63383 см-1 (т.е. ниже первого
потенциала ионизации атома Fe),
принадлежат к валентным электронным конфигурациям …4d64s2 (к этой конфигурации относится основное
электронное состояние атома 5D4), ...3d74s,...3d74d, ...3d64s4p, ...3d54s24p, …и ...3d8. Численные
значения уровней энергии и их статистических весов взяты прежде всего из сводки
Шугара и Корлиса [85SUG/COR],
которые выполнили критический анализ результатов спектральных исследований и
составили таблицы уровней энергии Fe
и его ионов. Рекомендованные в [85SUG/COR] данные были дополнены рядом уровней энергии
атома Fe, соответствующих
электронным конфигурациям ...3d74p, ...3d64s4p, ...3d54s24p. Эти уровни не наблюдались в спектре и их
энергии были оценены Ротом [80ROT].
Всего в расчете термодинамических функций было учтено 75 оцененных уровней с
суммарным статистическим весом 501 и энергией выше 42900 см-1.
Погрешности в оценке этих уровней могут достигать 300 см-1, для
экспериментально определенных величин энергии уровней погрешности составляют 1
– 3 см-1.
Термодинамические функции Fe(г) были вычислены по уравнениям (1.3) - (1.6), (1.9), (1.10), (1.23) - (1.25)
непосредственным суммированием по уровням энергии, приведенным в табл. Fe.3.
Погрешности вычисленных
термодинамических функций при Т < 3000
К определяются в основном неточностью фундаментальных физических постоянных;
при более высоких температурах погрешности увеличиваются из-за ошибок в оценке
ненаблюдавшихся уровней энергии, а также из-за возможной неполноты данных о
валентных состояниях атома Fe
с энергией ниже первого потенциала ионизации. При температурах, близких к
верхнему пределу, возникают ошибки из-за пренебрежения более высокими
состояниями, в том числе ридберговскими состояниями. Суммарные погрешности в Φ°(T)
составляют 0.02, 0.03, 0.1 и 1 Дж×К‑1×моль‑1 соответственно при Т
= 298.15, 3000, 6000 и 10000К.
Ранее таблицы термодинамических функций Fe(г) вычислялись неоднократно, в том числе в
сводке Хилзенрата и др. [64HIL/MES] (T < 10000K) исправочнике JANAF
[85CHA/DAV] (T < 6000 K). Кроме того, в работе [84HAL/GRA] были рассчитаны статистические суммы для Fe в интервале температур 2000 – 37000K. Результаты настоящего расчета хорошо
согласуются с величинами, приведенными в [85CHA/DAV], [64HIL/MES]:
максимальные расхождения с данными [64HIL/MES] составляют 0.008, 0.053 и 0.150 в значениях Φ°(T),
S°(Т) и Сp°(T)
при T = 10000K. Величины Φ°(T), рассчитанные по данным [84HAL/GRA], существенно отличаются от приведенных в
табл. Fe: расхождения
возрастают с температурой от 0.2 Дж×К‑1×моль‑1 при 2000K до 14.5 Дж×К‑1×моль‑1 при 10000K. Дать разумное объяснение этим расхождениям
не представляется возможным: по-видимому, в расчете [84HAL/GRA]
допущена ошибка.
Энтальпия образования одноатомного
железа
ΔfH°(Fe,
г, 298.15K) = 414 ± 2 кДж×моль‑1
соответствует принятым в
настоящем издании энтальпиям образования и сублимации Fe(к,ж).
АВТОРЫ
Юнгман В.С. yungman@yandex.ru
Гусаров А.В.a-gusarov@yandex.ru
27.05.96
Таблица Fe.3. Уровни энергии атома Fe, принятые для расчета термодинамических функций.
Электронная конфигурация |
Состояние |
Энергия (Ti), cм-1 |
Статистический вес (pi) |
...3d64s2 |
5D4 |
0 |
9 |
...3d64s2 |
5D3 |
415.932 |
7 |
...3d64s2 |
5D2 |
704.004 |
5 |
...3d64s2 |
5D1 |
888.129 |
3 |
...3d64s2 |
5D0 |
978.072 |
1 |
...3d7(4F)4s |
5F5 |
6928.266 |
11 |
...3d7(4F)4s |
5F4 |
7376.76 |
9 |
...3d7(4F)4s |
5F3 |
7728.056 |
7 |
...3d7(4F)4s |
5F2 |
7985.78 |
5 |
...3d7(4F)4s |
5F1 |
8154.71 |
3 |
...3d7(4F)4s |
3F4 |
11976.234 |
9 |
...3d7(4F)4s |
3F3 |
12560.93 |
7 |
...3d7(4F)4s |
3F2 |
12968.549 |
5 |
...3d7(4P)4s |
5P3 |
17550.175 |
7 |
...3d7(4P)4s |
5P2 |
17726.981 |
5 |
...3d7(4P)4s |
5P1 |
17927.376 |
3 |
...3d64s2 |
3P2 |
18378.181 |
5 |
...3d64s2 |
3P1 |
19552.473 |
3 |
...3d64s2 |
3P0 |
20037.813 |
1 |
...3d6(5D)4s4p(3P) |
7D5 |
19350.892 |
11 |
...3d6(5D)4s4p(3P) |
7D4 |
19562.44 |
9 |
...3d6(5D)4s4p(3P) |
7D3 |
19757.033 |
7 |
...3d6(5D)4s4p(3P) |
7D2 |
19912.494 |
5 |
...3d6(5D)4s4p(3P) |
7D1 |
20019.635 |
3 |
...3d64s2 |
3H6 |
19390.164 |
13 |
...3d64s2 |
3H5 |
19621.005 |
11 |
...3d64s2 |
3H4 |
19788.245 |
9 |
...3d64s2 |
3F4 |
20641.109 |
9 |
...3d64s2 |
3F3 |
20874.484 |
7 |
...3d64s2 |
3F2 |
21038.985 |
5 |
...3d7(2G)4s |
3G5 |
21715.73 |
11 |
...3d7(2G)4s |
3G4 |
21999.127 |
9 |
...3d7(2G)4s |
3G3 |
22249.428 |
7 |
...3d6(5D)4s4p(3P) |
7F6° |
22650.421 |
13 |
...3d6(5D)4s4p(3P) |
7F5° |
22845.868 |
11 |
...3d6(5D)4s4p(3P) |
7F4° |
22996.676 |
9 |
...3d6(5D)4s4p(3P) |
7F3° |
23110.937 |
7 |
...3d6(5D)4s4p(3P) |
7F2° |
23192.497 |
5 |
...3d6(5D)4s4p(3P) |
7F1° |
23244.834 |
3 |
...3d6(5D)4s4p(3P) |
7F0° |
23270.374 |
1 |
...3d7(4P)4s |
3P2 |
22838.318 |
5 |
...3d7(4P)4s |
3P1 |
22946.808 |
3 |
...3d7(4P)4s |
3P0 |
23051.742 |
1 |
...3d6(5D)4s4p(3P) |
7P4° |
23711.457 |
9 |
...3d6(5D)4s4p(3P) |
7P3° |
24180.864 |
7 |
...3d6(5D)4s4p(3P) |
7P2° |
24506.919 |
5 |
...3d64s2 |
3G5 |
23783.614 |
11 |
...3d64s2 |
3G4 |
24118.814 |
9 |
...3d64s2 |
3G3 |
24338.762 |
7 |
...3d7(2P)4s |
3P2 |
24335.759 |
5 |
...3d7(2P)4s |
3P1 |
24772.017 |
3 |
...3d7(2P)4s |
3P0 |
25091.597 |
1 |
...3d7(2G)4s |
1G4 |
24574.65 |
9 |
...3d6(5D)4s4p(3P) |
5D4° |
25899.987 |
9 |
...3d6(5D)4s4p(3P) |
5D3° |
26140.177 |
7 |
...3d6(5D)4s4p(3P) |
5D2° |
26339.691 |
5 |
...3d6(5D)4s4p(3P) |
5D1° |
26479.376 |
3 |
...3d6(5D)4s4p(3P) |
5D0° |
26550.476 |
1 |
...3d7(2H)4s |
3H6 |
26105.904 |
13 |
...3d7(2H)4s |
3H5 |
26351.039 |
11 |
...3d7(2H)4s |
3H4 |
26627.604 |
9 |
...3d7(2D)4s |
3D3 |
26224.966 |
7 |
...3d7(2D)4s |
3D1 |
26406.47 |
3 |
...3d7(2D)4s |
3D2 |
26623.73 |
5 |
...3d6(5D)4s4p(3P) |
5F5° |
26874.549 |
11 |
...3d6(5D)4s4p(3P) |
5F4° |
27166.819 |
9 |
...3d6(5D)4s4p(3P) |
5F3° |
27394.688 |
7 |
...3d6(5D)4s4p(3P) |
5F2° |
27559.581 |
5 |
...3d6(5D)4s4p(3P) |
5F1° |
27666.346 |
3 |
...3d7(2P)4s |
1P1 |
27543.004 |
3 |
...3d7(2D)4s |
1D2 |
28604.606 |
5 |
...3d7(2H)4s |
1H5 |
28819.946 |
11 |
...3d6(5D)4s4p(3P) |
5P3° |
29056.321 |
7 |
...3d6(5D)4s4p(3P) |
5P2° |
29469.02 |
5 |
...3d6(5D)4s4p(3P) |
5P1° |
29732.733 |
3 |
...3d64s2 |
1I6 |
29313.003 |
13 |
...3d64s2 |
3D1 |
29320.028 |
3 |
...3d64s2 |
3D2 |
29356.74 |
5 |
...3d64s2 |
3D3 |
29371.811 |
7 |
...3d64s2 |
1G4 |
29798.933 |
9 |
...3d6(5D)4s4p(3P) |
3F4° |
31307.243 |
9 |
...3d6(5D)4s4p(3P) |
3F3° |
31805.067 |
7 |
...3d6(5D)4s4p(3P) |
3F2° |
32133.986 |
5 |
...3d6(5D)4s4p(3P) |
3D3° |
31322.611 |
7 |
...3d6(5D)4s4p(3P) |
3D2° |
31686.346 |
5 |
...3d6(5D)4s4p(3P) |
3D1° |
31937.316 |
3 |
...3d8 |
3F4 |
32873.619 |
9 |
...3d8 |
3F3 |
33412.74 |
7 |
...3d8 |
3F2 |
33765.29 |
5 |
...3d74p(4F) |
5D4° |
33095.937 |
9 |
...3d74p(4F) |
5D3° |
33507.12 |
7 |
...3d74p(4F) |
5D2° |
33801.567 |
5 |
...3d74p(4F) |
5D1° |
34017.098 |
3 |
...3d74p(4F) |
5D0° |
34121.58 |
1 |
...3d7(4F)4p |
5F5° |
33695.394 |
11 |
...3d7(4F)4p |
5F4° |
34039.513 |
9 |
...3d7(4F)4p |
5F3° |
34328.749 |
7 |
...3d7(4F)4p |
5F2° |
34547.206 |
5 |
...3d7(4F)4p |
5F1° |
34692.144 |
3 |
...3d6(5D)4s4p(3P) |
3P2° |
33946.029 |
5 |
...3d6(5D)4s4p(3P) |
3P1° |
34362.871 |
3 |
...3d6(5D)4s4p(3P) |
3P0° |
34555.6 |
1 |
...3d64s2 |
1D2 |
34636.78 |
5 |
...3d7(4F)4p |
5G5° |
34782.416 |
11 |
...3d7(4F)4p |
5G6° |
34843.94 |
13 |
...3d7(4F)4p |
5G4° |
35257.319 |
9 |
...3d7(4F)4p |
5G3° |
35611.619 |
7 |
...3d7(4F)4p |
5G2° |
35856.4 |
5 |
...3d7(4P)4p |
3G5° |
35379.206 |
11 |
...3d7(4P)4p |
3G4° |
35767.561 |
9 |
...3d7(4P)4p |
3G3° |
36079.366 |
7 |
...3d7(4F)4p |
3F4° |
36686.164 |
9 |
...3d7(4F)4p |
3F3° |
37162.74 |
7 |
...3d7(4F)4p |
3F2° |
37521.157 |
5 |
...3d6(5D)4s4p(1P) |
5P3° |
36766.962 |
7 |
...3d6(5D)4s4p(1P) |
5P2° |
37157.557 |
5 |
...3d6(5D)4s4p(1P) |
5P1° |
37409.542 |
3 |
...3d7(2F)4s |
3F2 |
36940.56 |
5 |
...3d7(2F)4s |
3F3 |
36975.6 |
7 |
...3d7(2F)4s |
3F4 |
37045.96 |
9 |
...3d7(4F)4p |
3D3° |
38175.35 |
7 |
...3d7(4F)4p |
3D2° |
38678.032 |
5 |
...3d7(4F)4p |
3D1° |
38995.73 |
3 |
...3d6(5D)4s4p(1P) |
5D4° |
39625.8 |
9 |
...3d6(5D)4s4p(1P) |
5D3° |
39969.844 |
7 |
...3d6(5D)4s4p(1P) |
5D2° |
40231.332 |
5 |
...3d6(5D)4s4p(1P) |
5D1° |
40404.506 |
3 |
...3d6(5D)4s4p(1P) |
5D0° |
40491.274 |
1 |
...3d5(6S)4s24p |
7P2° |
40052.03 |
5 |
...3d5(6S)4s24p |
7P3° |
40207.086 |
7 |
...3d5(6S)4s24p |
7P4° |
40421.85 |
9 |
...3d6(5D)4s4p(1P) |
5F5° |
40257.307 |
11 |
...3d6(5D)4s4p(1P) |
5F4° |
40594.429 |
9 |
...3d6(5D)4s4p(1P) |
5F3° |
40842.151 |
7 |
...3d6(5D)4s4p(1P) |
5F2° |
41018.05 |
5 |
...3d6(5D)4s4p(1P) |
5F1° |
41130.627 |
3 |
...4d64s2 |
1F3 |
40534.14 |
7 |
...3d6(3P)4s4p(3P) |
5S2° |
40894.986 |
5 |
...3d6(3P)4s4p(3P) |
5P3° |
42532.736 |
7 |
...3d6(3P)4s4p(3P) |
5P2° |
42859.77 |
5 |
...3d6(3P)4s4p(3P) |
5P1° |
43079.026 |
3 |
...3d6(3H)4s4p(3P) |
5G6° |
42784.35 |
13 |
...3d6(3H)4s4p(3P) |
5G5° |
42911.908 |
11 |
...3d6(3H)4s4p(3P) |
5G4° |
43022.975 |
9 |
...3d6(3H)4s4p(3P) |
5G3° |
43137.479 |
7 |
...3d6(3H)4s4p(3P) |
5G2° |
43210.021 |
5 |
...3d6(3H)4s4p(3P) |
5I7 |
42901 |
15 |
...3d6(3H)4s4p(3P) |
5I6 |
42903 |
13 |
...3d6(3H)4s4p(3P) |
5I5 |
42955 |
11 |
...3d6(3H)4s4p(3P) |
5I8 |
43021 |
17 |
...3d6(3H)4s4p(3P) |
5I4 |
43048 |
9 |
...3d6(3H)4s4p(3P) |
5H5° |
42991.62 |
11 |
...3d6(3H)4s4p(3P) |
5H4° |
43108.9 |
9 |
...3d6(3H)4s4p(3P) |
5H6° |
43321.08 |
13 |
...3d6(3H)4s4p(3P) |
5H3° |
43325.958 |
7 |
...3d6(3H)4s4p(3P) |
5H7° |
43385 |
15 |
...3d6(3F)4s4p(3P) |
5D4° |
43499.496 |
9 |
...3d6(3F)4s4p(3P) |
5D3° |
43922.664 |
7 |
...3d6(3F)4s4p(3P) |
5D2° |
44183.62 |
5 |
...3d6(3F)4s4p(3P) |
5D1° |
44411.151 |
3 |
...3d6(3F)4s4p(3P) |
5D0° |
44458.92 |
1 |
...3d6(3F)4s4p(3P) |
5F3° |
44166.203 |
7 |
...3d6(3F)4s4p(3P) |
5F5° |
44243.673 |
11 |
...3d6(3F)4s4p(3P) |
5F2° |
44285.443 |
5 |
...3d6(3F)4s4p(3P) |
5F1° |
44378.38 |
3 |
...3d6(3F)4s4p(3P) |
5F4° |
44415.07 |
9 |
...3d6(3P)4s4p(3P) |
5D4° |
44022.535 |
9 |
...3d6(3P)4s4p(3P) |
5D3° |
44551.33 |
7 |
...3d6(3P)4s4p(3P) |
5D2° |
44664.068 |
5 |
...3d6(3P)4s4p(3P) |
5D1° |
44760.75 |
3 |
...3d6(3P)4s4p(3P) |
5D0° |
44826.88 |
1 |
...3d7(4P)4p |
5S2° |
44511.806 |
5 |
...3d6(3P)4s4p(3P) |
3D3° |
45220.676 |
7 |
...3d6(3P)4s4p(3P) |
5D2° |
45281.831 |
5 |
...3d6(3P)4s4p(3P) |
5D1° |
45551.763 |
3 |
...3d6(3H)4s4p(3P) |
3G5° |
45294.846 |
11 |
...3d6(3H)4s4p(3P) |
3G4° |
45428.397 |
9 |
...3d6(3H)4s4p(3P) |
3G3° |
45562.97 |
7 |
...3d6(3F)4s4p(3P) |
5G6° |
45608.31 |
13 |
...3d6(3F)4s4p(3P) |
5G5° |
45726.117 |
11 |
...3d6(3F)4s4p(3P) |
5G4° |
45833.2 |
9 |
...3d6(3F)4s4p(3P) |
5G3° |
45913.488 |
7 |
...3d6(3F)4s4p(3P) |
5G2° |
45964.959 |
5 |
...3d6(3H)4s4p(3P) |
3I7° |
45978 |
15 |
...3d6(3H)4s4p(3P) |
3I6° |
46026.94 |
13 |
...3d6(3H)4s4p(3P) |
3I5° |
46135.88 |
11 |
...3d7(4P)4p |
5P3° |
46137.1 |
7 |
...3d7(4P)4p |
5P2° |
46313.57 |
5 |
...3d7(4P)4p |
5P1° |
46410.4 |
3 |
...3d6(3P)4s4p(3P) |
3S1° |
46600.814 |
3 |
...3d7(4P)4p |
3P0° |
46672.527 |
1 |
...3d7(4P)4p |
3P2° |
46727.068 |
5 |
...3d7(4P)4p |
3P1° |
46901.82 |
3 |
...3d6(3F)4s4p(3P) |
3F4 |
46720.836 |
9 |
...3d6(3F)4s4p(3P) |
3F3 |
47092.707 |
7 |
...3d6(3F)4s4p(3P) |
3F2 |
47197.014 |
5 |
...3d7(4P)4p |
5D4 |
46889.143 |
9 |
...3d7(4P)4p |
5D3 |
47017.188 |
7 |
...3d7(4P)4p |
5D2 |
47136.072 |
5 |
...3d7(4P)4p |
5D0 |
47171.48 |
1 |
...3d7(4P)4p |
5D1 |
47177.225 |
3 |
...3d7(4P)4p |
5D3 |
46744.988 |
7 |
...3d7(4P)4p |
5D2 |
46888.51 |
5 |
...3d7(4P)4p |
5D1 |
47272.016 |
3 |
...3d6(3H)4s4p(3P) |
3H6° |
46982.34 |
13 |
...3d6(3H)4s4p(3P) |
3H5° |
47008.366 |
11 |
...3d6(3H)4s4p(3P) |
3H4° |
47106.477 |
9 |
...3d6(3G)4s4p(3P) |
5G6° |
47363.369 |
13 |
...3d6(3G)4s4p(3P) |
5G5° |
47420.229 |
11 |
...3d6(3G)4s4p(3P) |
5G4° |
47590.047 |
9 |
...3d6(3G)4s4p(3P) |
5G3° |
47693.227 |
7 |
...3d6(3G)4s4p(3P) |
5G2° |
47831.15 |
5 |
...3d6(3P)4s4p(3P) |
1D2° |
47419.674 |
5 |
...3d7(2G)4p |
1G4 |
47452.716 |
9 |
...3d7(4P)4p |
3S1 |
47555.598 |
3 |
...3d6(3G)4s4p(3P) |
5F5 |
47606.094 |
11 |
...3d6(3G)4s4p(3P) |
5F4 |
47929.999 |
9 |
...3d6(3G)4s4p(3P) |
5F3 |
48122.928 |
7 |
...3d6(3G)4s4p(3P) |
5F2 |
48238.844 |
5 |
...3d6(3G)4s4p(3P) |
5F1 |
48350.601 |
3 |
...3d6(3F)4s4p(3P) |
3G4 |
47812.118 |
9 |
...3d6(3F)4s4p(3P) |
3G3 |
47834.218 |
7 |
...3d6(3F)4s4p(3P) |
3G5 |
47834.542 |
11 |
...3d6(3G)4s4p(3P) |
5H7 |
47900 |
15 |
...3d6(3G)4s4p(3P) |
5H6 |
48016 |
13 |
...3d6(3G)4s4p(3P) |
5H5 |
48231.27 |
11 |
...3d6(3G)4s4p(3P) |
5H4 |
48361.878 |
9 |
...3d6(3G)4s4p(3P) |
5H3 |
48475.668 |
7 |
...3d5(6S)4s24p |
5P3 |
47966.59 |
7 |
...3d5(6S)4s24p |
5P2 |
48163.438 |
5 |
...3d5(6S)4s24p |
5P1 |
48289.865 |
3 |
...3d6(3H)4s4p(3P) |
1I6 |
48029 |
13 |
...3d6(3P)4s4p(3P) |
1S0 |
48231 |
1 |
...3d6(3P)4s4p(3P) |
3P2 |
48304.638 |
5 |
...3d6(3P)4s4p(3P) |
3P0 |
48460.098 |
1 |
...3d6(3P)4s4p(3P) |
3P1 |
48516.135 |
3 |
...3d7(2G)4p |
1H5 |
48382.597 |
11 |
...3d7(2G)4p |
1H4 |
48702.526 |
9 |
...3d7(2G)4p |
3F4 |
49108.89 |
9 |
...3d7(2G)4p |
3F3 |
49242.881 |
7 |
...3d7(2G)4p |
3F2 |
49433.121 |
5 |
...3d6(3F)4s4p3 |
3D3 |
49135.022 |
7 |
...3d6(3F)4s4p3 |
3D2 |
49242.593 |
5 |
...3d6(3F)4s4p3 |
3D1 |
49297.62 |
3 |
...3d6(3F)4s4p3 |
1F3 |
49227.12 |
7 |
...3d7(2G)4p |
3H6 |
49434.156 |
13 |
...3d7(2G)4p |
3H5 |
49604.415 |
11 |
...3d7(2G)4p |
3H4 |
49726.977 |
9 |
...3d7(2G)4p |
3G5 |
49460.89 |
11 |
...3d7(2G)4p |
3G4 |
49627.877 |
9 |
...3d7(2G)4p |
3G3 |
49850.581 |
7 |
...3d7(2G)4p |
3P0 |
49951.341 |
1 |
...3d7(2G)4p |
3P1 |
50043.205 |
3 |
...3d7(2G)4p |
3P2 |
50186.83 |
5 |
...3d6(5D)4s(6D)4d |
7F6 |
50342.14 |
13 |
...3d6(5D)4s(6D)4d |
7F5 |
50833.428 |
11 |
...3d6(5D)4s(6D)4d |
7F3 |
51148.859 |
7 |
...3d6(5D)4s(6D)4d |
7F4 |
51192.27 |
9 |
...3d6(5D)4s(6D)4d |
7F1 |
51207.991 |
3 |
...3d6(5D)4s(6D)4d |
7F2 |
51331.044 |
5 |
...3d6(5D)4s(6D)4d |
7F0 |
51000 |
1 |
...3d6(5D)4s(6D)4d |
7D5 |
50377.913 |
11 |
...3d6(5D)4s(6D)4d |
7D4 |
50807.991 |
9 |
...3d6(5D)4s(6D)4d |
7D3 |
50861.816 |
7 |
...3d6(5D)4s(6D)4d |
7D2 |
50998.641 |
5 |
...3d6(5D)4s(6D)4d |
7D1 |
51048.112 |
3 |
...3d6(5D)4s(6D)4d |
5D4 |
50423.136 |
9 |
...3d6(5D)4s(6D)4d |
5D3 |
50534.391 |
7 |
...3d6(5D)4s(6D)4d |
5D2 |
50698.624 |
5 |
...3d6(5D)4s(6D)4d |
5D1 |
50880.098 |
3 |
...3d6(5D)4s(6D)4d |
5D0 |
50980.98 |
1 |
...3d6(5D)4s(6D)4d |
7P4 |
50475.287 |
9 |
...3d6(5D)4s(6D)4d |
7P3 |
50611.26 |
7 |
...3d6(5D)4s(6D)4d |
7P2 |
50861.321 |
5 |
...3d6(5D)4s(6D)4d |
5G6 |
50522.946 |
13 |
...3d6(5D)4s(6D)4d |
5G5 |
50703.866 |
11 |
...3d6(5D)4s(6D)4d |
5G4 |
50979.578 |
9 |
...3d6(5D)4s(6D)4d |
5G3 |
51219.017 |
7 |
...3d6(5D)4s(6D)4d |
5G2 |
51370.13 |
5 |
...3d6(3P)4s4p(3P) |
1P1 |
50570 |
3 |
...3d7(2G)4p |
1F3 |
50586.874 |
7 |
...3d6(3F)4s4p(3P) |
1G4 |
50613.972 |
9 |
...3d6(5D)4s(6D)4d |
7G7 |
50651.72 |
15 |
...3d6(5D)4s(6D)4d |
7G6 |
50967.826 |
13 |
...3d6(5D)4s(6D)4d |
7G5 |
51228.555 |
11 |
...3d6(5D)4s(6D)4d |
7G4 |
51334.909 |
9 |
...3d6(5D)4s(6D)4d |
7G3 |
51460.516 |
7 |
...3d6(5D)4s(6D)4d |
7G2 |
51539.712 |
5 |
...3d6(5D)4s(6D)4d |
7G1 |
51566.82 |
3 |
...3d6(3G)4s4p(3P) |
3H6 |
51023.152 |
13 |
...3d6(3G)4s4p(3P) |
3H5 |
51068.71 |
11 |
...3d6(3G)4s4p(3P) |
3H4 |
51409.117 |
9 |
...3d6(5D)4s(6D)4d |
5F5 |
51103.187 |
11 |
...3d6(5D)4s(6D)4d |
5F4 |
51461.672 |
9 |
...3d6(5D)4s(6D)4d |
5F3 |
51604.102 |
7 |
...3d6(5D)4s(6D)4d |
5F2 |
51705.007 |
5 |
...3d6(5D)4s(6D)4d |
5F1 |
51754.49 |
3 |
...3d6(5D)4s(6D)4d |
5S2 |
51148.883 |
5 |
...3d7(2D)4p |
3F2 |
51201.284 |
5 |
...3d7(2D)4p |
3F4 |
51304.603 |
9 |
...3d7(2D)4p |
3F3 |
51365.308 |
7 |
...3d6(3G)4s4p(3P) |
3G5 |
51373.909 |
11 |
...3d6(3G)4s4p(3P) |
3G4 |
51668.189 |
9 |
...3d6(3G)4s4p(3P) |
3G3 |
51825.773 |
7 |
...3d6(5D)4s(6D)4d |
7S3 |
51570.084 |
7 |
...3d6(3H)4s4p(3P) |
1H5 |
51630.172 |
11 |
...3d6(3F)4s4p(3P) |
1D2 |
51708.309 |
5 |
...3d7(2P)4p |
1D2 |
51762.067 |
5 |
...3d6(5D)4s(6D)4d |
5P3 |
51837.24 |
7 |
...3d6(5D)4s(6D)4d |
5P1 |
52019.67 |
3 |
...3d6(5D)4s(6D)4d |
5P2 |
52067.46 |
5 |
...3d7(2P)4p |
3D3 |
51969.079 |
7 |
...3d7(2P)4p |
3D2 |
52296.899 |
5 |
...3d7(2P)4p |
3D1 |
52512.445 |
3 |
...3d7(2P)4p |
1P1 |
52180.804 |
3 |
...3d7(a2D)4p |
3D3 |
52213.226 |
7 |
...3d7(a2D)4p |
3D2 |
52682.915 |
5 |
...3d7(a2D)4p |
3D1 |
53229.942 |
3 |
...3d7(2H)4p |
3H6 |
52431.418 |
13 |
...3d7(2H)4p |
3H5 |
52613.084 |
11 |
...3d7(2H)4p |
3H4 |
52768.721 |
9 |
...3d7(2H)4p |
3I6 |
52513.549 |
13 |
...3d7(2H)4p |
3I7 |
52655 |
15 |
...3d7(2H)4p |
3I5 |
52898.971 |
11 |
...3d7(2D)4p |
3P1 |
52857.79 |
3 |
...3d7(2D)4p |
3P2 |
52916.292 |
5 |
...3d7(2D)4p |
3P0 |
53518 |
1 |
...3d7(4F)4d |
5F5 |
53061.24 |
11 |
...3d7(4F)4d |
5F4 |
53393.68 |
9 |
...3d7(4F)4d |
5F3 |
53830.973 |
7 |
...3d7(4F)4d |
5F2 |
54257.505 |
5 |
...3d7(4F)4d |
5F1 |
54386.189 |
3 |
...3d7(2H)4p |
1I6 |
53093.521 |
13 |
...3d7(4F)4p |
5D4 |
53155.09 |
9 |
...3d7(4F)4p |
5D3 |
53545.847 |
7 |
...3d7(4F)4p |
5D2 |
53966.68 |
5 |
...3d7(4F)4p |
5D1 |
54132.55 |
3 |
...3d7(4F)4p |
5D0 |
54500 |
1 |
...3d7(4F)4d |
5P3 |
53160.49 |
7 |
...3d7(4F)4d |
5P2 |
53568.68 |
5 |
...3d7(4F)4d |
5P1 |
53925.22 |
3 |
...3d7(4F)4d |
5G6 |
53169.17 |
13 |
...3d7(4F)4d |
5G5 |
53281.7 |
11 |
...3d7(4F)4d |
5G4 |
53768.969 |
9 |
...3d7(4F)4d |
5G3 |
54161.132 |
7 |
...3d7(4F)4d |
5G2 |
54375.68 |
5 |
...3d7(4F)4d |
5H7 |
53275.16 |
15 |
...3d7(4F)4d |
5H6 |
53352.98 |
13 |
...3d7(4F)4d |
5H5 |
53874.26 |
11 |
...3d7(4F)4d |
5H4 |
54237.16 |
9 |
...3d7(4F)4d |
5H3 |
54491.04 |
7 |
...3d6(3D)4s4p(3p |
5F2 |
53275.23 |
5 |
...3d6(3D)4s4p(3p |
5F1 |
53550 |
3 |
...3d6(3D)4s4p(3p |
5F3 |
53661.09 |
7 |
...3d6(3D)4s4p(3p |
5F4 |
53731 |
9 |
...3d6(3D)4s4p(3p |
5F5 |
54013.74 |
11 |
...3d6(3G)4s4p(3p |
3F4 |
53328.87 |
9 |
...3d6(3G)4s4p(3p |
3F3 |
53763.272 |
7 |
...3d6(3G)4s4p(3p |
3F2 |
54187 |
5 |
...3d6(3G)4s4p(3p |
1H5 |
53722.4 |
11 |
...3d7(4F)4d |
3G5 |
53739.433 |
11 |
...3d7(4F)4d |
3G4 |
54066.53 |
9 |
...3d7(4F)4d |
3G3 |
54379.4 |
7 |
...3d7(2P)4p |
3S1 |
53744 |
3 |
...3d7(4F)4d |
3D3 |
53747.51 |
7 |
...3d7(4F)4d |
3D2 |
54066.758 |
5 |
...3d7(4F)4d |
3D1 |
54449.29 |
3 |
...3d6(3D)4s4p(3P) |
5D1 |
53808.353 |
3 |
...3d6(3D)4s4p(3P) |
5D3 |
53891.52 |
7 |
...3d6(3D)4s4p(3P) |
5D2 |
53916 |
5 |
...3d6(3D)4s4p(3P) |
5D0 |
53945 |
1 |
...3d6(3D)4s4p(3P) |
5D4 |
54301.334 |
9 |
...3d7(2D)4p |
1F3 |
53821 |
7 |
...3d7(4F)4d |
3H6 |
57840.64 |
13 |
...3d7(4F)4d |
3H5 |
54266.72 |
11 |
...3d7(4F)4d |
3H4 |
54555.41 |
9 |
...3d7(2H)4p |
3G5 |
53983.284 |
11 |
...3d7(2H)4p |
3G4 |
54237.415 |
9 |
...3d7(2H)4p |
3G3 |
54600.346 |
7 |
...3d6(3D)4s4p(3P) |
5P3 |
54004.78 |
7 |
...3d6(3D)4s4p(3P) |
5P2 |
54112.218 |
5 |
...3d6(3D)4s4p(3P) |
5P1 |
54271.057 |
3 |
...3d6(1I)4s4p(3P) |
3K6 |
54180 |
13 |
...3d6(1I)4s4p(3P) |
3K7 |
54293 |
15 |
...3d6(1I)4s4p(3P) |
3K8 |
54430 |
17 |
...3d7(2P)4p |
1S0 |
54736 |
1 |
...3d6(3G)4s4p(3P) |
1G4 |
54810.841 |
9 |
...3d7(4F)4d |
3P2 |
54879.68 |
5 |
...3d7(4F)4d |
3P1 |
55376.08 |
3 |
...3d7(4F)4d |
3P0 |
55726.5 |
1 |
...3d7(4F)4d |
3F4 |
54683.35 |
9 |
...3d7(4F)4d |
3F3 |
55124.93 |
7 |
...3d7(4F)4d |
3F2 |
55378.8 |
5 |
...3d7(2D)4p |
1P1 |
55274 |
3 |
...3d6(1G)4s4p(3P) |
3H5 |
55429.815 |
11 |
...3d6(1G)4s4p(3P) |
3H4 |
55446 |
9 |
...3d6(1G)4s4p(3P) |
3H3 |
55489.77 |
7 |
...3d7(2H)4p |
1H5 |
55525.54 |
11 |
...3d7(2D)4p |
1D2 |
55754.239 |
5 |
...3d6(3G)4s4p(3P) |
2F3 |
55790.673 |
7 |
...3d6(1G)4s4p(3P) |
3G4 |
55908.538 |
9 |
...3d6(1G)4s4p(3P) |
3G5 |
55907.171 |
11 |
...3d6(1G)4s4p(3P) |
3G3 |
56097.829 |
7 |
...3d6(1I)4s4p(3P) |
3H6 |
56333.957 |
13 |
...3d6(1I)4s4p(3P) |
3H5 |
56382.662 |
11 |
...3d6(1I)4s4p(3P) |
3H4 |
56423.279 |
9 |
...3d6(1G)4s4p(3P) |
3F4 |
56592.699 |
9 |
...3d6(1G)4s4p(3P) |
3F3 |
56783.317 |
7 |
...3d6(1G)4s4p(3P) |
3F2 |
56858.659 |
5 |
...3d6(3D)4s4p(3P) |
3P2 |
56608 |
5 |
...3d6(3D)4s4p(3P) |
3P1 |
56937 |
3 |
...3d6(3D)4s4p(3P) |
3P0 |
57021 |
1 |
...3d7(2H)4p |
1G4 |
56951.286 |
9 |
...3d6(1I)4s4p(3P) |
3I7 |
57027.52 |
15 |
...3d6(1I)4s4p(3P) |
3I6 |
57070.21 |
13 |
...3d6(1I)4s4p(3P) |
3I5 |
57104.22 |
11 |
...3d6(3D)4s4p(3P) |
3D1 |
57190 |
3 |
...3d6(3D)4s4p(3P) |
3D2 |
57232 |
5 |
...3d6(3D)4s4p(3P) |
3D3 |
57249 |
7 |
...3d6(3D)4s4p(3P) |
3F4 |
57550 |
9 |
...3d6(3D)4s4p(3P) |
3F3 |
57641 |
7 |
...3d6(3D)4s4p(3P) |
3F2 |
57708.747 |
5 |
...3d6(5D)4s(4D)4d |
5D4 |
57697.55 |
9 |
...3d6(5D)4s(4D)4d |
5D3 |
57813.94 |
7 |
...3d6(5D)4s(4D)4d |
5D2 |
57974.129 |
5 |
...3d6(5D)4s(4D)4d |
5D1 |
58125 |
3 |
...3d6(5D)4s(4D)4d |
5D0 |
58275 |
1 |
...3d6(1S)4s4p(3P) |
3P2 |
57744 |
5 |
...3d6(1S)4s4p(3P) |
3P1 |
57868 |
3 |
...3d6(1S)4s4p(3P) |
3P0 |
58112 |
1 |
...3d6(5D)4s(4D)4d |
5G6 |
58001.84 |
13 |
...3d6(5D)4s(4D)4d |
5G5 |
58271.46 |
11 |
...3d6(5D)4s(4D)4d |
5G4 |
58520.14 |
9 |
...3d6(5D)4s(4D)4d |
5G3 |
58710.05 |
7 |
...3d6(5D)4s(4D)4d |
5G2 |
58824.77 |
5 |
...3d6(5D)4s(4D)4d |
1D2 |
58213.121 |
5 |
...3d6(3P)4s4p(1P) |
3D3 |
58483 |
7 |
...3d6(3P)4s4p(1P) |
3D2 |
58811 |
5 |
...3d6(3P)4s4p(1P) |
3D1 |
59648 |
3 |
...3d6(3H)4s4p(1P) |
3I7 |
58509 |
15 |
...3d6(3H)4s4p(1P) |
3I6 |
58689 |
13 |
...3d6(3H)4s4p(1P) |
3I5 |
58811 |
11 |
...3d6(3H)4s4p(1P) |
3G5 |
58529 |
11 |
...3d6(3H)4s4p(1P) |
3G4 |
58663 |
9 |
...3d6(3H)4s4p(1P) |
3G3 |
58765 |
7 |
...3d6(3P)4s4p(1P) |
3S1 |
59369 |
3 |
...3d6(3D)4s4p(3P) |
1D2 |
59670 |
5 |
...3d6(1D)4s4p(3P) |
3F3 |
59686 |
7 |
...3d6(1D)4s4p(3P) |
3F2 |
59891 |
5 |
...3d6(1D)4s4p(3P) |
3F4 |
59999 |
9 |
...3d6(3F)4s4p(1P) |
3G5 |
59926.62 |
11 |
...3d6(3F)4s4p(1P) |
3G4 |
60172.06 |
9 |
...3d6(3F)4s4p(1P) |
3G3 |
60364.76 |
7 |
...3d6(3D)4s4p(3P) |
1F3 |
60022 |
7 |
...3d6(3D)4s4p(3P) |
1P1 |
60220 |
3 |
...3d6(3H)4s4p(1P) |
1H6 |
60365.7 |
13 |
...3d6(3H)4s4p(1P) |
1H5 |
60549.18 |
11 |
...3d6(3H)4s4p(1P) |
1H4 |
60757.68 |
9 |
...3d6(3F)4s4p(1P) |
3F5 |
60677.23 |
11 |
...3d6(3F)4s4p(1P) |
3F4 |
60754.71 |
9 |
...3d6(3F)4s4p(1P) |
3F3 |
60806.654 |
7 |
...3d6(3F)4s4p(1P) |
3D3 |
60820 |
7 |
...3d6(3F)4s4p(1P) |
3D2 |
60953 |
5 |
...3d6(3F)4s4p(1P) |
3D1 |
60993 |
3 |
...3d6(1D)4s4p(3P) |
3P2 |
60857 |
5 |
...3d6(1D)4s4p(3P) |
3P0 |
61179 |
1 |
...3d6(1D)4s4p(3P) |
3P1 |
61199 |
3 |
...3d6(1D)4s4p(3P) |
3D3 |
61504 |
7 |
...3d6(1D)4s4p(3P) |
3D2 |
61657 |
5 |
...3d6(1D)4s4p(3P) |
3D1 |
61670 |
3 |
...3d6(3G)4s4p(1P) |
3F4 |
61651 |
9 |
...3d6(3G)4s4p(1P) |
3F3 |
62334 |
7 |
...3d6(3G)4s4p(1P) |
3F2 |
62336 |
5 |
...3d6(3G)4s4p(1P) |
3G5 |
61700 |
11 |
...3d6(3G)4s4p(1P) |
3G3 |
61949 |
7 |
...3d6(3G)4s4p(1P) |
3G4 |
62140 |
9 |
...3d6(3P)4s4p(1P) |
3P2 |
61786 |
5 |
...3d6(3P)4s4p(1P) |
3P1 |
61847 |
3 |
...3d6(3P)4s4p(1P) |
3P0 |
61899 |
1 |
...3d6(3G)4s4p(1P) |
3H6 |
63053 |
13 |
...3d6(3G)4s4p(1P) |
3H5 |
63413 |
11 |
...3d6(3G)4s4p(1P) |
3H4 |
63610 |
9 |
...3d7(2F)4d |
1D2 |
63383 |
5 |
|
Список литературы
[64HIL/MES] |
Hilsenrath J., Messina C.G., Evans W.H. - 'Tables of Ideal Gas Thermodynamic Functions for 73 atoms and their first and second ions to 10000K.', Washington: AD-606163, NBS, 1964 |
[80ROT] |
Roth C. - Atom. Data and Nucl. Data Tables, 1980, 25, No.2, p. 91-184 |
[84HAL/GRA] |
Halenka J., Grabowski B. - Astron. Astrophys., Suppl. Ser., 1984, 57, No.1, p.43-49 |
[85CHA/DAV] |
Chase M.W., Davies C.A., Downey J.R., Frurip D.J., McDonald R. A., Syverud A.N. - 'JANAF thermochemical tables. Third edition. J. Phys. and Chem. Ref. Data.', 1985, 14, No.Suppl. 1, p.1-1856 |
[85SUG/COR] |
Sugar J., Corliss C. - J. Phys. and Chem. Ref. Data, 1985, 14, No.Suppl.2, p.1-664 |