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Молекула |
Состояние |
Te |
we |
wexe |
Be |
a1×103 |
De×107 |
|
re |
|
|
|
|
см‑1 |
|
|
|
Å |
|
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|
|
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|
| 63Cu1H |
X1S |
0 |
1941.26 |
37.51a |
7.9441 |
256.3b |
5200c |
|
1.46263 |
| |
A1S |
23434.2 |
1698.4 |
44.0d |
6.874 |
263 |
4350 |
|
1.5724 |
| |
b3P0+ |
26420 |
1669.7 |
51.2 |
6.582 |
290 |
4050 |
|
1.6069 |
| |
a3Se |
26490 |
|
|
5.9f |
|
|
|
1.64 |
| |
C1 |
27270.4 |
1627.3 |
86 |
6.553 |
352 |
4760 |
|
1.6104 |
| |
c1 |
28161 |
1388.7 |
85 |
6.43 |
420 |
|
|
1.626 |
| |
e2(3P) |
27958g |
|
|
|
|
|
|
|
| |
bD2 |
28470 |
1475 |
|
6.7 |
|
|
|
1.59 |
| |
E1S+ |
39299 |
574 |
-3.6h |
3.093 |
-36i |
3800 |
|
2.344 |
| |
d3Pj |
41000 |
1760 |
|
7.8 |
|
|
|
1.48 |
| |
D1P |
44669 |
1804.0 |
55 |
7.72 |
310 |
760 |
|
1.484 |
| 63Cu19F |
X1S+ |
0 |
621.55 |
3.494 |
0.379403 |
3.2298a |
5.655 |
|
1.74493 |
| |
a3S |
14591.43b |
674.20 |
4.138 |
0.380995c |
|
4.905c |
|
1.74128c |
| |
b3P |
17530.93d |
647.078 |
3.457 |
0.374763c |
|
5.102c |
|
1.75570c |
| |
A1S+ |
19717.48 |
656.04 |
3.63 |
0.37134 |
2.855 |
4.72 |
|
1.76377 |
| |
B1P |
20258.70 |
643.73 |
3.66 |
0.37556 |
2.975 |
5.33 |
|
1.75384 |
| |
c3D |
22805.15 |
616.42 |
3.329 |
0.35942 |
2.81 |
4.91 |
|
1.79278 |
| |
C1D |
25000e |
|
|
|
|
|
|
|
| 63Cu35Cl |
X1S+a |
0 |
417.60 |
1.617 |
0.1782473 |
1.013b |
1.299c |
|
2.05119 |
| |
a3S+1 |
19001.4 |
409.2 |
1.72 |
0.1701872d |
|
1.1616d |
|
2.0992d |
| |
b3P1 |
20484.17 |
401.55 |
1.63 |
0.1704735e |
1.3986 |
1.2581d,e |
|
2.09744 |
| |
b3P0 |
20631.09 |
399.08 |
1.50 |
0.170948 |
0.9009 |
1.2426d |
|
2.09453 |
| |
A1P |
22969.5 |
395.6 |
1.9 |
0.169336 |
0.0966 |
1.3272d |
|
2.10447 |
| |
B1S+ |
23074.5 |
405.3 |
1.7 |
0.1681726 |
1.1152 |
0.943d |
|
2.11174 |
| |
c3D1 |
25285.3 |
387.1 |
1.67 |
0.1626 |
0.92 |
1.2 |
|
2.148 |
| 63Cu79Br |
X1S+a |
0 |
314.819 |
0.95755b |
0.1019262 |
0.45212c |
0.42720d |
|
2.17345 |
| |
a3S+ |
19830,5 |
294.49 |
1.525e |
0.09415f |
|
0.28f |
|
2.2614f |
| |
b3P1 |
20496.06 |
297 |
1.332g |
0.096509 |
0.65 |
0.389 |
|
2.2336 |
| |
A1P |
23042.58 |
284.69 |
1.347 |
0.096200 |
0.494h |
0.439i |
|
2.2372 |
| |
B1S+ |
23460.92 |
294.944 |
1.1336 |
0.094306 |
0.433j |
0.382k |
|
2.2596 |
| |
c3D1 |
25538.6 |
281.9 |
1.35 |
0.0952 |
0.5 |
0.405 |
|
2.2489 |
| 63Cu127I |
X1S+a |
0 |
264.897 |
0.715 |
0.0732873 |
0.2839 |
0.2244 |
|
2.33833 |
| |
a3S+1 |
19734.2 |
213.3 |
2.22 |
0.06571 |
0.43 |
0.24d |
|
2.469 |
| |
b3P0 |
21867.3 |
229.7 |
0.53 |
0.068233d |
|
0.242d |
|
2.423 |
| |
A1P |
22957.5 |
212.8 |
0.92 |
0.067040 |
0.42 |
0.25 |
|
2.445 |
| |
B1S+ |
24001.70 |
229.51 |
0.99 |
0.065602 |
0.281c |
0.216f |
|
2.4715 |
|
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Примечания: Ниже все постоянные приведены в см-1.
CuH: aweye = 0.067; ba2 = 0.0015; cb1 = -0.073×10-4; dуровни v = 2, 3 и 4 возмущены; eприведено Te(CuD); fоценено из возмущений в b3P0+; gЗначение T0 рассчитано из анализа возмущений уровня c1(v = 0); hweye = -0.27; ia2 = -4.8×10-3; jA = +117, колебательная нумерация ненадежна;
CuF: aa2 = 1.23×10-7; bприведено T0, l = 22.33516, g = -0.36413; cпостоянные для уровня v = 0; dприведено T0; A = -412.846; eоценка
CuCl: aоцененные состояния;
| Состояние |
a3S+0 |
b3P2 |
c3D2,3 |
C1D |
| Ti |
19000 |
20350 |
26000 |
29000 |
ba2 = 2.01×10-6, a3 = 2.0×10-9; cb1 = 7.81×10-11 , He = -2.0×10-14; dдля уровня v = 0; el-удвоение.
CuBr:aоцененные состояния;
| Состояние |
a3S0 |
b3P2 |
b3P0+ |
b3P0- |
c3D2,3 |
C1D |
| Ti |
19740 |
19850 |
20490 |
21500 |
24200 |
27100 |
|
|
|
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|
|
bweye = 1.71×10-3; ca2 = 6.705×10-7; db1 = -1.41×10-10 , He = -0.73×10-14; eweye = 0.0239; fпостоянныедляуровня v = 0; gweye = -0.125; ha2 = -3.9×10-6; ib1 = 4.05×10-10 , He = -2.5×10-14; ja2 = -0.67×10-6; kb1 = -2.3×10-10 , He = -1.0×10-14
CuI: aоцененные состояния;
| pi |
1 |
8 |
3 |
2 |
8 |
4 |
| Ti |
19650 |
21100 |
22600 |
24000 |
31200 |
38500 |
