Role of water fluid in the formation of solid phase oxides

Ivakin Yu.D. , Danchevskaya M.N. , Torbin S.N. , Kreisberg V.A. , Martynova L.F.

Proceedings of the 7-th Meeting on Supercritical Fluids. Particles Design, Materials and Natural Products Processing, 1, p.525 - 531, (2000)

Abstract. The role of an aqueous medium in solid-phase processes of structure transformation of hydroxides and oxides of metals is shown. The restructuring of oxides proceeds due to processes of hydroxylation - dehydroxylation of oxides structure in conditions of quasiequilibrium with a water vapour.

Laboratory of Catalysis and Gas Electrochemistry